Soldering applications include (Ref. 1):
• Fixing and manufacturing electronics including circuit boards
• Crafting jewelry, metalwork, and stained glass
• Building professions such as roofers, plumbers, gutter repairmen, and electricians
What are solder fumes (smoke)?Solder fumes are composed of metal vapors from the solder and gas from the evaporated solder flux (Ref. 2). Soldering melts metal alloys with low melting points to create a bond releasing metal vapors into the air. When using a solder flux, the soldering iron heats the solder flux to aid in the bond formation turning the solder flux into a gaseous state. This combination of exposure to solder vapors and gases can cause the operator lasting health effects depending on the type of solder and the solder flux, as well as the duration and frequency of the application.
Soldering Fumes Health EffectsExposure to soldering fumes health effects mainly depends on the type of solder and the solder flux chemical composition. The most popular solders used contain lead, rosin, or are lead-free composed of tin, silver, and copper (Ref. 3). Other specialized solders include alloys of beryllium, aluminum, gold, iron, and brass. Overall, exposure to solder fumes can lead to the development of occupational asthma directly caused from work environment exposure (Ref. 4). The operator may become sensitized to toxic and irritating substances leading to the development or worsening of asthma after exposure. Symptoms include chest tightness, wheezing, and shortness of breath. In particular, certain alloys of solders, such as lead based solder and beryllium based solder, provoke more severe and long-lasting health effects than others, such as tin, silver, and gold. The health hazards for common solder components are detailed below:
Lead – May cause lead poisoning, kidney disease, hypertension, and weight loss. Targets the gastrointestinal tract, nervous system, kidneys, and blood (Ref. 5). Symptoms include metallic taste in the mouth, nausea, vomiting, headache, cramps, nervousness, and insomnia.
Tin – Considered relatively harmless but may generate benign pneumoconiosis, or eye, skin, and respiratory system irritation (Ref. 6).
Silver – May create throat irritation, blue gray eyes, nasal septum irritation, and gastrointestinal disturbance (Ref. 7).
Copper – Can produce eye and upper respiratory irritation, and metal fume fever (Ref. 8). Metal fume fever symptoms include fever, chills, aches, pains, nausea, and dizziness.
Beryllium – Classified as a Group 1 carcinogen. Can lead to beryllium sensitization possibly causing chronic beryllium disease with symptoms of shortness of breath, coughing, fatigue, night sweats, and fever. Can worsen over time forming granulomas or masses of immune cells on the lungs (Ref. 9).
Aluminum – May provoke irritation to eyes, skin, respiratory system (Ref. 10).
Gold – Regarded as generally harmless but exercise caution with certain alloys (Ref. 7).
Iron – May lead to siderosis a form of pneumoconiosis (Ref. 11).
Brass (Zinc Oxide) – Can cause metal fume fever (Ref. 8).
In addition to the exposure to solder fumes, solder fluxes containing fluoride and rosin based solder fluxes fumes can provoke lasting health symptoms. Inhalation of fluoride should be monitored due to the toxic nature of hydrogen fluoride and boron trifluoride. Both substances can cause eye, skin, nose, and throat irritation. Hydrogen fluoride exposure may cause pneumonitis, while boron trifluoride can lead to bronchitis and pulmonary edema due to the excess of fluid in the lungs (Ref. 12 & 13).
Rosin core solders and rosin based solder fluxes contain rosin which comes from the resins of pine trees. When heated, rosin creates a flux fume called colophony containing a complex mix of particulate and gases (Ref. 14). The colophony particulates deposit deep within the lungs leading to lung damage and the possible development of occupational asthma (Ref. 15). The colophony gases include acetone, methyl alcohol, methane, ethane, CO, and CO2 and aliphatic aldehydes with exposure causing upper respiratory irritations and possible formation of cancer (Ref. 16).
Soldering Safety OSHATo safeguard employee health, OSHA requires employers to monitor air quality and restrict exposure to below mandated standards. OSHA legally enforces the permissible exposure limit (PEL) to help provide safe working environments. OSHA recommends employers to use ventilation or fume extraction systems at the source to restrict exposure to harmful soldering fumes. Although not legally enforced, NIOSH sets a recommended exposure limit (REL) based on all scientific study data available for the substance. The following chart summarizes the OSHA PELs and the NIOSH RELs for soldering and solder flux fumes contaminants (Ref. 17).
|Substance||OSHA PEL||NIOSH REL|
|Aluminum (respirable)||5 mg/m3||5 mg/m3|
|Boron trifluoride||1 ppm||1 ppm|
|Copper (fume)||0.1 mg/m3||0.1 mg/m3|
|Hydrogen fluoride||3 ppm||3 ppm|
|Iron oxide (fume)||10 mg/m3||5 mg/m3|
|Lead||0.05 mg/m3||0.05 mg/m3|
|Rosin core solder
|0.1 mg/m3||0.1 mg/m3|
|Silver||0.01 mg/m3||0.01 mg/m3|
|Zinc oxide||5 mg/m3||5 mg/m3|
Your Rights as an EmployeeAs an employee, you have the right to a safe breathing work environment. The OSHA Safety and Health Act of 1970 places responsibility on employers to provide a safe working environment free from harms likely or known to cause lasting health effects (Ref. 18). This responsibility includes substances without a permissible exposure limit. Employees have the right to proper ventilation in order to maintain optimal respiratory health and safety.
Soldering PPE RequirementsIn addition to proper ventilation, employees must wear proper PPE to protect from other soldering hazards. Protective clothing, such as a long-sleeved shirt, pants, and gloves, prevents burns from splashes of hot solder. Protective eyewear, such as safety glasses or goggles, protects the eyes while soldering and clipping wires (Ref. 19).
Soldering Safety PPTThe powerpoint below showcases the information displayed in this blog. Download for easy reference.
Solder Fume ExtractionSentry Air Systems offers a wide variety of solder fume extraction systems including benchtop, portable, and wall mounted units. These systems use ductless technology filtering out particulate and fumes with high quality filtration options. For filtering particulate filter options include HEPA (up to 99.97% efficiency on particles down to 0.3 microns), ULPA (up to 99.9995% efficiency on particles down to 0.12 microns), ASHRAE (up to 95% efficiency on particles down to 0.5 microns). For applications that need chemical fume extraction, we offer activated carbon filters or specialty blended filter media (acid gas, ammonia, aldehyde, and mercury). Select units allow for dual filtration options enabling the removal of chemical fumes as well as particulate. Ductless systems enable simple installation without the requirement for makeup air production or expensive ductwork. Flame retardant filter media provides an added safety benefit for heat-based solder fume extraction systems.
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Sources1. Deziel, Chris. “10 Different Uses for a Soldering Iron.” Hunker, 8 September 2018. https://www.hunker.com/13402927/10-different-uses-for-a-soldering-iron.
2. Mraz, Stephen. “What’s the Difference Between Soldering, Brazing and Welding.” Machine Design, 14 July 2015. https://www.machinedesign.com/fasteners/whats-difference-between-soldering-brazing-and-welding.
3. Burris, Matthew. “Types of Solder.” Lifewire, 13 November 2019. https://www.lifewire.com/types-of-solder-flux-818850.
4. “Occupational Asthma.” Mayo Clinic, 22 May 2018. https://www.mayoclinic.org/diseases-conditions/occupational-asthma/symptoms-causes/syc-20375772.
5. NIOSH Pocket Guide to Chemical Hazards. “Lead.” 4 October 2019. https://www.cdc.gov/niosh/npg/npgd0368.html.
6. NIOSH Pocket Guide to Chemical Hazards. “Tin.” 4 October 2019. https://www.cdc.gov/niosh/npg/npgd0613.html.
7. NIOSH Pocket Guide to Chemical Hazards. “Silver.” 4 October 2019. https://www.cdc.gov/niosh/npg/npgd0557.html.
8. NIOSH Pocket Guide to Chemical Hazards. “Zinc Oxide.” 4 October 2019. https://www.cdc.gov/niosh/npg/npgd0675.html.
9. Occupational Safety and Health Administration. “Health Effects: Beryllium.” https://www.osha.gov/SLTC/beryllium/healtheffects.html.
10. NIOSH Pocket Guide to Chemical Hazards. “Aluminum.” 4 October 2019. https://www.cdc.gov/niosh/npg/npgd0022.html.
11. NIOSH Pocket Guide to Chemical Hazards. “Iron Oxide Dust and Fume.” 4 October 2019. https://www.cdc.gov/niosh/npg/npgd0344.html.
12. NIOSH Pocket Guide to Chemical Hazards. “Hydrogen Fluoride.” 4 October 2019. https://www.cdc.gov/niosh/npg/npgd0334.html.
13. NIOSH Pocket Guide to Chemical Hazards. “Boron Trifluoride.” 4 October 2019. https://www.cdc.gov/niosh/npg/npgd0062.html.
14. “The Health Risks of Solder Flux Fumes.” Metcal Blog, 21 August 2017. http://blog.okinternational.com/metcal/the-health-risks-of-solder-flux-fumes.
15. University of Cambridge. “Soldering Safety.” Department of Engineering Health & Safety. https://safety.eng.cam.ac.uk/safe-working/copy_of_soldering-safety.
16. NIOSH Pocket Guide to Chemical Hazards. “Rosin core solder, pyrolysis products (as formaldehyde),” 4 October 2019. https://www.cdc.gov/niosh/npg/npgd0547.html
17. Occupational Safety and Health Administration. “OSHA Annotated Table Z-1.” https://www.osha.gov/dsg/annotated-pels/tablez-1.html.
18. Occupational Safety & Health Administration, “Occupational Safety and Health Act of 1970.” http://www.osha.gov/pls/oshaweb/owadisp.show_document?p_table=OSHACT&p_id=2743.
19. Oregon State University. “Safety Instruction – Soldering Safety.” January 2017. https://ehs.oregonstate.edu/sites/ehs.oregonstate.edu/files/pdf/si/soldering_safety_si.pdf.